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T91 / P91 Welding: Weld Metal Analysis

In order to obtain optimum weld metal in term of chemical composition and mechanical properties, the welding process and weld consumables(wire, rod, flux, electrode, etc) for T91/ P91 steel shall be carefully selected. It is very difficult to find a filler metal to meet the same chemical composition requirements as the base metal while achieve its minimum impact toughness.

Large O.D P91 pipe welding, SANMEN power plant Unit #1.

Large-O.D P91 (ASME SA335) pipe welding, SANMEN power plant Unit #1.

The content of each element shall be carefully controlled, especially nitrogen (N), manganese (Mn), nickel (Ni) and niobium (Nb). Nitrogen may form carbonitride which influences the creep rupture strength. It may improve both yield and tensile strengths but lower ductility and toughness of T91/ P91 steel. The Ni and Mn can improve the toughness of weld metal. However, the combination of Mn and Ni tends to lower the Ac1 temperature to the point where the PWHT temperature approaches the AC1, possibly causing partial transformation of microstructure of P91 weld metal. Nb has negative influence on the toughness but it improves the creep strength apparently. In conclusion: generally the total content of Mn+Ni shall be less than 1.5%; N content shall be restricted to approx. 0.04%; Nb content shall be slightly higher than 0.04%.

1. Typical Composition for T91/ P91 Weld Metal & Filler Metal

Welding Process / Filler MetalGTAW / Welding RodSMAW / ElectrodeSAW / WireWeld Metal
C0.100.090.110.11
Si0.200.200.300.30
Mn0.500.650.500.50
Cr9.009.009.008.50
Mo1.001.101.000.95
Ni0.800.800.800.75
Nb0.050.050.060.05
V0.200.200.200.20
N0.040.040.040.04
* The unit for all values is “%”.

2. Optimum Mechanical Properties for T91/ P91 Weld Metal

Welding ProcessPWHTYield Strength
min. MPa[ksi]
Tensile Strength
min. MPa[ksi]
Elongation
min. %
Impact Energy
Absorption, J
GTAW760°C/ 1400°F
Stress-Relieving
420[60.9]580[84.1]17%50
SMAW760°C for 2h
760°C for 4h
550[79.8]
500[72.5]
680[98.6]
620[89.9]
17%
18%
60
65
SAW760°C for 2h
750°C for 4h
540[78.3]700[101.5]20%47
*GTAW is also referred to as “TIG Welding” – tungsten inert gas welding.

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